If you're set on choosing a 5008, we can't really see why you wouldn't choose this Hybrid 136 version. It can't offer you the tax breaks of its Plug-in Hybrid and full-electric 5008 range stablemates, but its asking prices are vastly lower and its 48V engine can still run on electric power much of the time during urban motoring. It's certainly a big step forward from the old-shape conventional PureTech 130 un-electrified variant.
Engines like this for cars like this might not be a long term solution. But they're pretty good alternative right here, right now.

PEUGEOT i-connect advanced HD fully customisable touch screen, Navigation with Tom Tom Live updates and over the air map updates

Peugeot Open and Go (keyless entry and push button start)

PEUGEOT i-Cockpit - 21" HD panoramic curved display incorporating instrument panel and touchscreen with 3colour themes

Compact split leather mutifunction steering wheel with gloss black and satin chrom detailing

2x Isofix child seat fitting on 2nd row outer seats with zipped cover

Adaptive front passenger airbags with airbag deactivation function

Thatcham category 1 Perimetric and volumetric alarm with anti-lift detection

Central front armrest with ventilated storage compartment and LED lighting

19" BREDA diamond cut alloy wheels with star center cap in orbital black

Manual gear changes via steering mounted paddles

Drive modes select (Eco, normal and sport) with configurable ambient lighting

Advanced Emergency Braking System with radar (AEBS3) providing night detection of pedestrians and cyclists

Speed limit and traffic sign recognition and recommendation

ABS (Anti-lock Braking System) with (EBD) Electronic Brakeforce Distribution

Dynamic stability control (DSC) and Anti slip regulation (ASR)

Dark tinted privacy glass for rear door, Tailgate and Quarter windows

Front and rear electric windows with one touch

Door mirrors - Welcome lighting and integrated LED indicators

Wireless mirror screen with apple carplay and android auto

Bluetooth with two microphones (Connect up to 2 phones)

Wireless smartphone charger with status light and ambient lighting

Electric adjustable/heated/folding door mirrors

Insurance Group 1 - 50 Effective January 07

NCAP Overall Rating - Effective February 09

Standard manufacturers Battery warranty - Years

Standard manufacturers warranty - Mileage

Peugeot 5008

1.2 Hybrid 136 Allure 5dr e-DSC6